MersV1, Main, Exploration, bibRecord, 002411

[μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0)

Identifieur interne : 002411 ( Main/Exploration ); précédent : 002410; suivant : 002412

[μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0)

Auteurs : Omar Bin Shawkataly [Malaisie] ; Imthyaz Ahmed Khan [Malaisie] ; Siti Syaida Sirat [Malaisie] ; Chin Sing Yeap [Malaisie] ; Hoong-Kun Fun [Malaisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.

RBID : PMC:3051588

Abstract

The asymmetric unit of the title triangulo-triruthenium compound, [Ru₃(C₂₆H₂₄P₂)(C₁₈H₁₅Sb)(CO)₉], consists of two crystallographically independent molecules, A and B. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and phosphine ligands are equatorial with respect to the Ru₃ triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted benzene rings make dihedral angles of 38.7 (3), 71.5 (3) and 70.0 (3)° with each other in molecule A whereas these angles are 83.9 (3), 88.2 (3) and 56.8 (3)° in molecule B. Similarly, the dihedral angles between the two benzene rings are 80.7 (3) and 87.6 (3)° for the two diphenylphosphanyl groups in molecule A and 84.0 (3) and 72.6 (4)° in molecule B. In the crystal, molecules are linked into tetramers via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051588

DOI: 10.1107/S1600536810054218
PubMed: 21522852
PubMed Central: 3051588

Affiliations:

Malaisie

Le document en format XML

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<italic>P</italic>
:<italic>P</italic>
′]nonacarbonyl-1κ<sup>3</sup>
<italic>C</italic>
,2κ<sup>3</sup>
<italic>C</italic>
,3κ<sup>3</sup>
<italic>C</italic>
-(triphenylstibine-3κ<italic>Sb</italic>
)-<italic>triangulo</italic>
-triruthenium(0)</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">[μ-Bis(diphenylphosphanyl)ethane-1:2κ<sup>2</sup>
<italic>P</italic>
:<italic>P</italic>
′]nonacarbonyl-1κ<sup>3</sup>
<italic>C</italic>
,2κ<sup>3</sup>
<italic>C</italic>
,3κ<sup>3</sup>
<italic>C</italic>
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-triruthenium(0)</title>
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<front><div type="abstract" xml:lang="en"><p>The asymmetric unit of the title <italic>triangulo</italic>
-triruthenium compound, [Ru<sub>3</sub>
(C<sub>26</sub>
H<sub>24</sub>
P<sub>2</sub>
)(C<sub>18</sub>
H<sub>15</sub>
Sb)(CO)<sub>9</sub>
], consists of two crystallographically independent molecules, <italic>A</italic>
 and <italic>B</italic>
. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and phosphine ligands are equatorial with respect to the Ru<sub>3</sub>
 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted benzene rings make dihedral angles of 38.7 (3), 71.5 (3) and 70.0 (3)° with each other in molecule <italic>A</italic>
 whereas these angles are 83.9 (3), 88.2 (3) and 56.8 (3)° in molecule <italic>B</italic>
. Similarly, the dihedral angles between the two benzene rings are 80.7 (3) and 87.6 (3)° for the two diphenylphosphanyl groups in molecule <italic>A</italic>
 and 84.0 (3) and 72.6 (4)° in molecule <italic>B</italic>
. In the crystal, molecules are linked into tetramers <italic>via</italic>
 intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure.</p>
</div>
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Serveur d'exploration MERS

[μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0)

[μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0)

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Abstract

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	Serveur d'exploration MERS
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Serveur d'exploration MERS

[μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ2P:P′]nona­carbonyl-1κ3C,2κ3C,3κ3C-(triphenyl­stibine-3κSb)-triangulo-triruthenium(0)

[μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ2P:P′]nona­carbonyl-1κ3C,2κ3C,3κ3C-(triphenyl­stibine-3κSb)-triangulo-triruthenium(0)

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Abstract

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[μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0)

[μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0)